Largely improved toughness of poly(lactic acid) by unique electrospun fiber network structure of thermoplastic polyurethane. (December 2017)

• Record Type: Journal Article
• Authors: Sun, Haibin; Hu, Jing; Bai, Xue; Zheng, Zhipeng; Feng, Zhanbin; Ning, Nanying; Zhang, Liqun; Tian, Ming
• Is Part Of: Polymer testing. Volume 64(2017)
• Page Start: 250
• Page End: 253
• Publication Date: 2017-12
• Subjects: Mechanical properties -- Poly(lactic acid) -- Phase morphology -- Toughening -- Electrospinning; Polymers -- Testing -- Periodicals; Polymères -- Tests -- Périodiques; 620.1920287
• DOI: 10.1016/j.polymertesting.2017.10.012
• Languages: English
• ISSNs: 0142-9418

Abstract

Abstract: Oriented thermoplastic polyurethane (TPU) fiber and fiber network were first prepared by electrospinning. The as-prepared TPU fiber or fiber network was then pre-fixed in poly(lactic acid) (PLA)/TPU composite to improve the toughness of PLA. For comparison purpose, TPU/PLA composites with sea-island morphology were also prepared by traditional solution blending and mechanical blending. The results show that the toughness of PLA is greatly increased by the special pre-fixed oriented TPU fibers even at a low content, and the toughness is further increased by the TPU fiber network. Our results indicate for the first time that the toughening effect of special TPU fibers or fiber network is much better than that of traditional TPU with sea-island morphology. This study provides guidance to largely improve the toughness of PLA by designing the special phase morphology of TPU. Highlights: TPU/PLA composites with different phase morphology were prepared. The toughness of PLA was significantly improved by controlling the morphology of TPU. The toughening mechanism of TPU/PLA composites with different phase morphology of TPU was studied. TPU/PLA composites exhibit significantly improved tensile toughness at low TPU content (20 wt%). The toughening effect of TPU fibers or fiber network is much better than sea-island morphology at the same content.