Boratriazines: inducing luminescence through boron incorporation into a terpy-type framework. (26th September 2017)

• Record Type: Journal Article
• Authors: Yousaf, Muhammad; Yutronkie, Nathan J.; Castañeda, Raúl; Klein, Jacob A.; Brusso, Jaclyn
• Is Part Of: New journal of chemistry. Volume 41:Number 20(2017)
• Page Start: 12218
• Page End: 12224
• Publication Date: 2017-09-26
• Subjects: Chemistry -- Periodicals; Chimie -- Périodiques; 540
• DOI: 10.1039/c7nj02462b
• Languages: English
• ISSNs: 1144-0546

Abstract

Abstract : The synthesis and physicochemical properties of pyridyl and pyrimidyl functionalized 1, 3, 5, 2-triazaborinines are reported, along with the Lewis acid–base adduct pyrimidine-2-carboximidamide trifluoroborane, which forms as a side product in the reaction with the pyrimidyl substituents. Abstract : The synthesis and physicochemical properties of 2, 2-difluoro-4, 6-bis(2-pyridyl)-1, 3-dihydro-1, 3, 5, 2-triazaborinine (F2 -Py2 BTA ) and 2, 2-difluoro-4, 6-bis(2-pyrimidinyl)-1, 3-dihydro-1, 3, 5, 2-triazaborinine (F2 -Pm2 BTA ), prepared from their respective N -imidoylamidines, are presented. In addition, the preparation and characterization of the Lewis acid–base adduct of pyrimidine-2-carboximidamide trifluoroborane (PmAmBF3 ), which forms as a side product in the reaction with N -2-pyrimidylimidoyl-2-pyrimidylamidine, is also described.