A novel 2-D Mn selenidostannate(iv) incorporating high-nuclear Mn clusters with spin canting behavior. Issue 46 (9th November 2017)

• Record Type: Journal Article
• Authors: Zhou, Jian; Xiao, Hong; Zou, Hua-Hong; Liu, Xing
• Is Part Of: Dalton transactions. Volume 46:Issue 46(2017)
• Page Start: 16009
• Page End: 16013
• Publication Date: 2017-11-09
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c7dt03331a
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : The incorporation of a hepta-nuclear Mn cluster [Mn7 (ea)6 ] 8+ into a selenidostannate(iv ) framework leads to a novel 2-D Mn selenidostannate(iv ) with spin canting behavior. Abstract : A solvothermal reaction of SnCl4 ·5H2 O, Mn and Se in ethanolamine (Hea) yielded a novel 2-D Mn selenidostannate(iv ) [Mn7 (ea)6 (SnSe4 )2 ] n (1 ), which not only provides the first example of the incorporation of a hepta-nuclear Mn cluster [Mn7 (ea)6 ] 8+ into a selenidostannate(iv ) framework, but also shows unusual spin canting behavior.