Bromobismuthates: Cation-induced structural diversity and Hirshfeld surface analysis of cation–anion contacts. (8th January 2018)

• Record Type: Journal Article
• Authors: Adonin, Sergey A.; Gorokh, Igor D.; Novikov, Alexander S.; Samsonenko, Denis G.; Korolkov, Ilya V.; Sokolov, Maxim N.; Fedin, Vladimir P.
• Is Part Of: Polyhedron. Volume 139(2018)
• Page Start: 282
• Page End: 288
• Publication Date: 2018-01-08
• Subjects: Halometalate -- Halide complexes -- Bismuth -- Crystal structure -- Hirshfeld surface analysis; Chemistry, Inorganic -- Periodicals; Chimie inorganique -- Périodiques; Organometaalverbindingen; Anorganische chemie; 546.05
• DOI: 10.1016/j.poly.2017.11.002
• Languages: English
• ISSNs: 0277-5387

Abstract

Graphical abstract: Reactions of [BiBr6 ] 3− and bromide salts of various pyridinium cations in excess of HBr result in a series of bromobismuthate complexes of various geometry and nuclearity: [{BiBr4 } n ] n −, [Bi2 Br9 ] 3− and [Bi2 Br10 ] 4− . Hirshfeld surface analysis for 19 crystal structure was performed; impact of various X-Br contacts on the crystal structures is discussed. Abstract: Reactions of [BiBr6 ] 3− and bromide salts of various substituted pyridinium cations in excess of HBr result in a series of bromobismuthate anionic complexes of various geometry and nuclearity: [{BiBr4 } n ] n −, [Bi2 Br9 ] 3− and [Bi2 Br10 ] 4− . Hirshfeld surface analysis for 19 crystal structure was performed; impact of various X-Br contacts on the crystal structures is discussed.