Organic-inorganic hybrid crystals, (2, 4, 6-CH3PyH)3Sb2Cl9 and (2, 4, 6-CH3PyH)3Bi2Cl9. Crystal structure characterization and tunneling of CH3 groups studied by 1H NMR and neutron spectroscopy. (8th January 2018)

• Record Type: Journal Article
• Authors: Szklarz, P.; Jakubas, R.; Piecha-Bisiorek, A.; Bator, G.; Chański, M.; Medycki, W.; Wuttke, J.
• Is Part Of: Polyhedron. Volume 139(2018)
• Page Start: 249
• Page End: 256
• Publication Date: 2018-01-08
• Subjects: Haloantimonates(III) -- Halobismuthates(III) -- Inelastic neutron scattering -- 1H NMR -- CH3 tunneling; Chemistry, Inorganic -- Periodicals; Chimie inorganique -- Périodiques; Organometaalverbindingen; Anorganische chemie; 546.05
• DOI: 10.1016/j.poly.2017.10.030
• Languages: English
• ISSNs: 0277-5387

Abstract

Graphical abstract: The crystal structures of TMPCA and (TMPCB) at 100 K. Bi2 Cl9 3− – a face-sharing bi-octahedron, Sb2 Cl9 3− – two pyramids connected by a corner. INS for TMPCA at low temperatures. 1 H NMR spin lattice relaxation times. The tunneling of the methyl groups at low temperature. Abstract: The crystal structures of (2, 4, 6-CH3 PyH)3 Sb2 Cl9 (TMPCA) and (2, 4, 6-CH3 PyH)3 Bi2 Cl9 (TMPCB) (Py – pyridine) have been determined at 100 K by the single crystal X-ray diffraction method. TMPCA and TMPCB crystallize in the monoclinic C2 / c and triclinic P 1 polar space group, respectively. In both cases the asymmetric part is comprised of three nonequivalent 2, 4, 6-trimethylpyridinium cations and a discrete M2 Cl9 3− anion. The Bi2 Cl9 3− moiety forms a face-sharing bi-octahedron, whereas in a case of Sb2 Cl9 3− we deal with two pyramids connected by a corner. The inelastic neutron scattering spectra (INS) were recorded for TMPCA at low temperatures (4–50 K). Two peaks on each side of the central elastic line have been observed at ca. 4.8 and 2.9 μeV, the high energy peak exhibits an excitation energy value equal to ca. 6 meV. For TMPCA and TMPCB the 1 H NMR spin–lattice relaxation times, T 1, have been measured in the temperature region 15–410 K. The flattening of the T 1 (spin–lattice) vs . reciprocal temperature, 1/ T, dependence between 30 K and 15 K indicates the incoherent tunneling effect of the methyl group being treated as the quantum rotor. The conclusions drawn from the 1 H NMR results as regards to the tunneling of the CH3 groups in the pyridinium cations are consistent with the tunneling peaks observed in the INS spectra.