Sustainable utilization of waste palm oil and sulfonated carbon catalyst derived from coconut meal residue for biodiesel production. (January 2018)

• Record Type: Journal Article
• Authors: Thushari, Indika; Babel, Sandhya
• Is Part Of: Bioresource technology. Volume 248:Part A(2018)
• Page Start: 199
• Page End: 203
• Publication Date: 2018-01
• Subjects: Biodiesel -- Waste palm oil -- Carbon based solid acid catalyst -- Direct sulfonation -- Coconut meal residue; Biomass -- Periodicals; Biomass energy -- Periodicals; Bioremediation -- Periodicals; Agricultural wastes -- Periodicals; Factory and trade waste -- Periodicals; Organic wastes -- Periodicals; Bioénergie -- Périodiques; Déchets agricoles -- Périodiques; Déchets industriels -- Périodiques; Déchets organiques -- Périodiques; Déchets (Combustible) -- Périodiques; 662.88
• DOI: 10.1016/j.biortech.2017.06.106
• Languages: English
• ISSNs: 0960-8524

Abstract

Graphical abstract: Highlights: An economical, environmental benign sulfonated carbon catalyst is prepared from CMR. Successful activation of the catalyst is confirmed by XPS and FTIR. Catalyst can be employed for one-step biodiesel production from waste palm oil. A FAME yield of >92% was obtained at optimum conditions in a reflux system. Catalyst showed a good reusability for four consecutive cycles with >80% FAME yield. Abstract: In this study, an inexpensive, environmental benign acid catalyst is prepared using coconut meal residue (CMR) and employed for biodiesel production from waste palm oil (WPO). The total acid density of the catalyst is found to be 3.8 mmolg −1 . The catalyst shows a unique amorphous structure with 1.33 m 2 g −1 of surface area and 0.31 cm 3 g −1 of mean pore volume. Successful activation is confirmed by Fourier transform infrared (FT-IR) spectroscopy and X-ray photoelectron spectroscopy (XPS). The highest biodiesel yield of 92.7% was obtained from WPO in an open reflux system using the catalyst. Results show that biodiesel yield increases with increasing methanol:oil (molar ratio) and reaction time up to an optimum value. It is found that the catalyst can be reused for at least four cycles for >80% biodiesel yield. Fuel properties of the produced biodiesel meet international biodiesel standards.