Aluminum‐Doped Cesium Lead Bromide Perovskite Nanocrystals with Stable Blue Photoluminescence Used for Display Backlight. Issue 11 (31st July 2017)

• Record Type: Journal Article
• Authors: Liu, Ming; Zhong, Guohua; Yin, Yongming; Miao, Jingsheng; Li, Ke; Wang, Chengqun; Xu, Xiuru; Shen, Clifton; Meng, Hong
• Is Part Of: Advanced science. Volume 4:Issue 11(2017)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2017-07-31
• Subjects: anion‐exchange effect -- blue photoluminescence -- doping -- perovskite nanocrystals -- white‐light‐emitting diodes; Science -- Periodicals; 505
• DOI: 10.1002/advs.201700335
• Languages: English
• ISSNs: 2198-3844

Abstract

Abstract: Bright and stable blue emitters with narrow full‐width at half‐maxima are particularly desirable for applications in television displays and related technologies. Here, this study shows that doping aluminum (Al 3+ ) ion into CsPbBr3 nanocrystals (NCs) using AlBr3 can afford lead‐halide perovskites NCs with stable blue photoluminescence. First, theoretical and experimental analyses reveal that the extended band gap and quantum confinement effect of elongated shape give rise to the desirable blueshifted emission. Second, the aluminum ion incorporation path is rationalized qualitatively by invoking fundamental considerations about binding relations in AlBr3 and its dimer. Finally, the absence of anion‐exchange effect is corroborated when green CsPbBr3 and blue Al:CsPbBr3 NCs are mixed. Combinations of the above two NCs with red‐emitting CdSe@ZnS NCs result in UV‐pumped white light‐emitting diodes (LED) with an National Television System Committee (NTSC) value of 116% and ITU‐R Recommendation B.T. 2020 (Rec. 2020) of 87%. The color coordinates of the white LED are optimized at (0.32, 0.34) in CIE 1931. The results suggest that low‐cost, earth‐abundant, solution‐processable Al‐doped perovskite NCs can be promising candidate materials for blue down‐conversion layer in backlit displays. Abstract : Doping aluminum (Al 3+ ) ion into CsPbBr3 nanocrystals (NCs) can afford lead‐halide perovskite NCs with stable blue photoluminescence. Cation compositional engineering of perovskite NCs provides an additional way to rationally tune the photophysical property. By this way, emission spectra broadening and chromaticity drifting issues caused by fast anion exchange in different halide perovskite NCs based conversion layers can be avoid.