Harnessing the potential diversity of resinic diterpenes through visible light-induced sensitized oxygenation coupled to Kornblum–DeLaMare and Hock reactions. Issue 12 (7th September 2017)

• Record Type: Journal Article
• Authors: Laroche, Benjamin; Nay, Bastien
• Is Part Of: Organic chemistry frontiers. Volume 4:Issue 12(2017)
• Page Start: 2412
• Page End: 2416
• Publication Date: 2017-09-07
• Subjects: Chemistry, Organic -- Periodicals; 547.005
• DOI: 10.1039/c7qo00633k
• Languages: English
• ISSNs: 2052-4110

Abstract

Abstract : A biomimetic procedure for the late functionalization of resinic acids is reported, implementing photooxygenation by singlet oxygen, using visible light and a photosensitized, combined to the Kornblum–DeLaMare reaction or the Hock rearrangement. Abstract : A biomimetic procedure for the late-stage functionalization of various resinic acids is reported, implementing photooxygenation by singlet oxygen, using visible light and meso -tetraphenylporphyrin, combined to the Kornblum–DeLaMare reaction or the Hock rearrangement. In addition to giving access to several natural and unnatural diterpenes by the simplest manner, these transformations furnish biosynthetic clues expandable to other natural product families.