Electrocatalytic Oxidation of Benzaldehyde Oxime Using Potassium Perchlorate in Biphasic Medium. (2017)

• Record Type: Journal Article
• Authors: Joy, Biju; Balaganesh, M.; Joseph Selvaraj, S.
• Is Part Of: Materials today. Volume 4:Number 13(2017)
• Page Start: 12426
• Page End: 12436
• Publication Date: 2017
• Subjects: Undivided cell -- Selective oxidation -- Benzaldehyde oxime -- Potassium perchlorate -- Biphasic medium -- Benzaldehyde; Materials science -- Congresses -- Periodicals; 620.1
• DOI: 10.1016/j.matpr.2017.10.013
• Languages: English
• ISSNs: 2214-7853

Abstract

Abstract: Benzaldehyde oxime can be readily converted to the corresponding benzaldehyde in high yields. The electrochemical oxidation was optimized with various experimental parameters to result in the high yield of benzaldehyde (80%). The reaction was carried out with platinum electrodes at room temperature in an undivided cell within constant biphasic medium consisting of chloroform containing benzaldehyde oxime and an aqueous solution of potassium perchlorate as a mediator with a stoichiometric amount of H2 SO4 .