ChemInform Abstract: CO Extrusion in Homogeneous Gold Catalysis: Reactivity of Gold Acyl Species Generated Through Water Addition to Gold Vinylidenes. Issue 24 (June 2015)

• Record Type: Journal Article
• Authors: Bucher, Janina; Stoesser, Tim; Rudolph, Matthias; Rominger, Frank; Hashmi, A. Stephen K.
• Is Part Of: ChemInform. Volume 46:Issue 24(2015)
• Page Start: no
• Page End: no
• Publication Date: 2015-06
• Subjects: indan derivatives -- ring closure reactions, annulation reactions -- catalysis, phase‐transfer catalysis -- decarbonylation; Chemistry -- Abstracts -- Periodicals; 540.5
• DOI: 10.1002/chin.201524102
• Languages: English
• ISSNs: 0931-7597

Abstract

Abstract: A novel reactivity of gold vinylidenes is discovered through the addition reaction of water to gold vinylidene intermediates resulting in CO‐extrusion and cyclization to indenes.