Lifetime nanomanometry – high-pressure luminescence of up-converting lanthanide nanocrystals – SrF2:Yb3+, Er3+. Issue 41 (13th October 2017)

• Record Type: Journal Article
• Authors: Runowski, Marcin; Marciniak, Jędrzej; Grzyb, Tomasz; Przybylska, Dominika; Shyichuk, Andrii; Barszcz, Bolesław; Katrusiak, Andrzej; Lis, Stefan
• Is Part Of: Nanoscale. Volume 9:Issue 41(2017)
• Page Start: 16030
• Page End: 16037
• Publication Date: 2017-10-13
• Subjects: Nanoscience -- Periodicals; Nanotechnology -- Periodicals; 620.505
• DOI: 10.1039/c7nr04353h
• Languages: English
• ISSNs: 2040-3364

Abstract

Abstract : Bright green-yellow high-pressure luminescence of up-converting lanthanide nanocrystals – SrF2 :Yb 3+ /Er 3+, for lifetime nanomanometry. Abstract : Anti-Stokes luminescence of up-converting nanocrystals SrF2 :Yb 3+, Er 3+ can be used as a high pressure optical sensor alternative to the ruby fluorescence-scale. In nanocrystalline SrF2 :Yb 3+, Er 3+, high pressure reversibly shortens the emission lifetimes nearly linearly up to 5.29 GPa at least. Its advantage is the use of NIR (≈980 nm) radiation, highly penetrable for many materials. The shortening of up-conversion lifetimes has been attributed mainly to the changes in energy transfer rates, caused by decreased interatomic distances and increased overlap integrals between 4f electrons and the valence shells of ligand ions. The origin of high-pressure effects on the luminescence intensity, band ratio and their spectral position has been explained by the increased interactions and distortions of the crystal-field symmetry around the emitting ions in the compressed structure.