A new phase-matchable nonlinear optical silicate: Rb2ZnSi3O8. Issue 42 (20th October 2017)

• Record Type: Journal Article
• Authors: Zhao, Bingqing; Yang, Yi; Zhao, Sangen; Shen, Yaoguo; Li, Xianfeng; Li, Lina; Ji, Chengmin; Lin, Zheshuai; Luo, Junhua
• Is Part Of: Journal of materials chemistry. Volume 5:Issue 42(2017)
• Page Start: 11025
• Page End: 11029
• Publication Date: 2017-10-20
• Subjects: Materials -- Periodicals; Chemistry, Analytic -- Periodicals; Optical materials -- Research -- Periodicals; Electronics -- Materials -- Research -- Periodicals; 543.0284
• DOI: 10.1039/c7tc03000b
• Languages: English
• ISSNs: 2050-7526

Abstract

Abstract : A new asymmetric silicate Rb2 ZnSi3 O8 with a three-dimensional structure shows phase-matchability and enhanced second-harmonic generation as compared with α-SiO2 . Abstract : Nonlinear optical (NLO) crystals are key materials for generation of coherent light in solid state lasers. A new NLO material Rb2 ZnSi3 O8 is synthesized by the traditional solid-state reaction technique and its crystals are obtained by spontaneous crystallization using an Rb2 O–B2 O3 flux. It crystallizes in an asymmetric space group of C 2 (No. 5) and features a three-dimensional framework composed of SiO4 and ZnO4 tetrahedral groups. Remarkably, it exhibits a phase-matchable powder second harmonic generation approximately 2.5 times that of α-SiO2, which is well known to be non-phase-matchable. The first-principle calculations reveal that the Si–O and Zn–O tetrahedra determine the optical properties in the Rb2 ZnSi3 O8 crystal and may be the origin of the phase matching behavior in Rb2 ZnSi3 O8 . The UV-visual-near-infrared diffuse reflectance spectrum shows that Rb2 ZnSi3 O8 has a wide transparency window down to the deep-UV spectral region. In addition, Rb2 ZnSi3 O8 is non-hygroscopic. These results suggest that Rb2 ZnSi3 O8 is a potential deep-UV NLO crystal.