Mechanical properties of Ropaque hollow nanoparticles. (22nd November 2017)

• Record Type: Journal Article
• Authors: Zhu, Liwen; Nguyen, Duc; Davey, Tim; Baker, Matthew; Such, Chris; Hawkett, Brian S.; Neto, Chiara
• Is Part Of: Polymer. Volume 131(2017)
• Page Start: 10
• Page End: 16
• Publication Date: 2017-11-22
• Subjects: Hollow particles -- AFM -- Mechanical properties -- Nanoindentation; Polymers -- Periodicals; Polymerization -- Periodicals; Polymères -- Périodiques; Polymérisation -- Périodiques; 547.7
• DOI: 10.1016/j.polymer.2017.10.030
• Languages: English
• ISSNs: 0032-3861

Abstract

Abstract: The elastic properties and strength upon compression of commercial Ropaque polystyrene hollow particles were investigated by atomic force microscopy (AFM). These particles are commonly used in paints as opacifying agents, as their internal air void effectively scatters light. A sharp AFM tip was used to apply a point load to the particle surface, and increased to probe both the elastic and plastic deformation of the shell, and then further until the shell broke. For small deformations, the deformation increased linearly with applied force. The Young's modulus was calculated by accounting for the effect of the rigid substrate, and compared to the modulus obtained from the Reissner and Hertz models. The minimum stress needed to destroy the integrity of the shell was extracted and found to be smaller than or close to that of silica hollow particles with different shell thickness tested in the literature. Graphical abstract: Highlights: The mechanical properties of Ropaque hollow particles were investigated by AFM. The Young's modulus was calculated by using three models. The minimum stress needed to pierce the shell was extracted.