Transmission electron microscopy studies and modeling of 3D reciprocal space of ω forming alloy. (November 2017)

• Record Type: Journal Article
• Authors: Alphy George, ; Sharma, Vinayak; Divakar, R.; Sabeena, M.; Mohandas, E.
• Is Part Of: Micron. Volume 102(2017)
• Page Start: 73
• Page End: 87
• Publication Date: 2017-11
• Subjects: Trigonal ω phase -- ω formation -- β transition metal alloy -- Phase contrast imaging -- Fourier filtering -- Reciprocal space modeling -- Collapse mechanism -- Ti-Mo alloy -- Multi slice simulation -- Simulated electron diffraction pattern -- Diffuse streaking; Microscopy -- Periodicals; Electron Probe Microanalysis -- Periodicals; Microscopy -- Periodicals; Microscopie -- Périodiques; Microscopy; Periodicals; 502.82
• DOI: 10.1016/j.micron.2017.08.004
• Languages: English
• ISSNs: 0968-4328

Abstract

Graphical abstract: Highlights: Identified the fine features appear in diffraction patterns of ω forming β alloy. Comparison of simulated diffraction patterns with SADP has revealed the uncoupling of diffuse arcs with ω variants. Predicted the possibility of P3m1 space group for trigonal ω by simulation experiments. Trigonal ω is imaged in three various zone axes (<110>β, <113>β and <102>β) solely by phase contrast microscopy. Experimental evidence for variation in degree of collapse for various ω particles is given with simulation support. By addressing the de Fontaine's model, it is rectified that the sphere of intensity will not fit in fcc lattice. Refined the de Fontaine's model by using hollow sphere of patterned intensity. Abstract: Initial stage of ω phase formation and associated anomalous features that appear in diffraction patterns of a metastable β transition metal alloy have been investigated in this study with the aid of transmission electron microscopy, simulation and modeling. The paper explores discrete features that emerge in selected area diffraction patterns of quenched Ti-15wt%Mo alloy and analyzes the correlation between ω reflections and diffuse arcs by considering all variants of ω phase as per the formation kinetics of ω phase in β matrix while quenching. Superimposed simulated diffraction patterns have been compared with experimental counterparts and it is deduced that there is lack of congruence between ω reflections and diffuse arcs even after considering trigonal ω with varying degrees of displacement. Direct lattice imaging of trigonal ω in β matrix has been demonstrated by phase contrast microscopy coupled with Fourier filtering techniques. By investigating the nature of ω reflections and diffuse arcs with the aid of electron diffraction pattern calculations and phase contrast microscopy, it is shown that, existing model of three-dimensional (3D) reciprocal space of ω forming alloy at quenched stage is not complete. A new model incorporating a patterned intensity distribution is fitted at the octahedral sites of an fcc reciprocal lattice whose planar intersections with Ewald's sphere show a better fit with the observed experimental diffraction patterns.