Hierarchically three-level Ni3(VO4)2@NiCo2O4 nanostructure based on nickel foam towards highly efficient alkaline hydrogen evolution. (1st December 2017)

• Record Type: Journal Article
• Authors: Shang, Xiao; Chi, Jing-Qi; Lu, Shan-Shan; Dong, Bin; Liu, Zi-Zhang; Yan, Kai-Li; Gao, Wen-Kun; Chai, Yong-Ming; Liu, Chen-Guang
• Is Part Of: Electrochimica acta. Volume 256(2017)
• Page Start: 100
• Page End: 109
• Publication Date: 2017-12-01
• Subjects: hierarchical structure -- Ni3(VO4)2 -- NiCo2O4 -- alkaline -- hydrogen evolution reaction; Electrochemistry -- Periodicals; Electrochemistry, Industrial -- Periodicals; 541.37
• DOI: 10.1016/j.electacta.2017.10.017
• Languages: English
• ISSNs: 0013-4686

Abstract

Graphical abstract: Highlights: Three level hierarchical nanostructures of Ni3 (VO4 )2 @NiCo2 O4 /NF were synthesized. Ni3 (VO4 )2 @NiCo2 O4 /NF provide more active sites and faster mass and charge transfer. Ni3 (VO4 )2 @NiCo2 O4 /NF demonstrate excellent activity and stability for HER. Designing hierarchical nanostructures of oxides may be a promising way for HER. Abstract: Designing mixed transition metal oxides with advantageous nanostructure is efficient access to highly-efficient electrocatalysts for hydrogen evolution reaction (HER) in water electrolysis due to more exposed active sites and synergistic effects in mixed metals. A hierarchically three-level nanostructure combining two types of mixed transition metal oxides on nickel foam (Ni3 (VO4 )2 @NiCo2 O4 /NF) has been synthesized through a two-step hydrothermal process. The hierarchically three level nanostructure comprises porous nickel foam as robust and conductive substrate in the bottom, vertical and uniform NiCo2 O4 nanowires arrays in the intermediate, and top-coated Ni3 (VO4 )2 nanoparticles in 10 nm. The triple hierarchical nanostructure of Ni3 (VO4 )2 @NiCo2 O4 /NF is favorable for enlarging surface areas, exposing more active sites, promoting mass and charge transfer and accelerating HER process. Ni3 (VO4 )2 @NiCo2 O4 /NF electrode can afford a current density of 10 mA cm −2 at a moderate overpotential of 113 mV with robust stability for at least 12 h. It may provide a new strategy to design triple hierarchical nanostructures based on earth-abundant transition metals to achieve large-scale production of hydrogen through water electrolysis in alkaline.