High‐Fidelity Noncovalent Synthesis of Hydrogen‐Bonded Macrocyclic Assemblies1. Issue 23 (17th April 2015)

• Record Type: Journal Article
• Authors: Montoro‐García, Carlos; Camacho‐García, Jorge; López‐Pérez, Ana M.; Bilbao, Nerea; Romero‐Pérez, Sonia; Mayoral, María J.; González‐Rodríguez, David
• Is Part Of: Angewandte Chemie international edition. Volume 54:Issue 23(2015)
• Page Start: 6780
• Page End: 6784
• Publication Date: 2015-04-17
• Subjects: chelates -- noncovalent interactions -- nucleosides -- self‐assembly -- supramolecular chemistry; Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.201501321
• Languages: English
• ISSNs: 1433-7851

Abstract

Abstract: A hydrogen‐bonded cyclic tetramer is assembled with remarkably high effective molarities from a properly designed dinucleoside monomer. This self‐assembled species exhibits an impressive thermodynamic and kinetic stability and is formed with high fidelities within a broad concentration range. Abstract : Fine design of a dinucleoside monomer leads to hydrogen‐bonded macrocyclic tetramer assemblies with high effective molarities and remarkable thermodynamic and kinetic stability. The behavior of these assemblies in various solvents is discussed.