A green approach to magnetically-hard electrically-conducting polyaniline/CoFe2O4 nanocomposites. (6th April 2015)

• Record Type: Journal Article
• Authors: Della Pina, Cristina; Ferretti, Anna Maria; Ponti, Alessandro; Falletta, Ermelinda
• Is Part Of: Composites science and technology. Volume 110(2015)
• Page Start: 138
• Page End: 144
• Publication Date: 2015-04-06
• Subjects: A. Nano composites -- A. Nano particles -- A. Polymer-matrix composites (PMCs) -- B. Magnetic properties -- Polyaniline; Composite materials -- Periodicals; Composite materials; Fibrous composites; Periodicals; 620.118
• DOI: 10.1016/j.compscitech.2015.02.007
• Languages: English
• ISSNs: 0266-3538

Abstract

Abstract: Magnetically-hard, electrically-conducting polyaniline/CoFe2 O4 nanocomposites were prepared by oxidative polymerization of N -(4-aminophenyl)aniline using molecular oxygen or hydrogen peroxide as the oxidants and magnetic CoFe2 O4 nanoparticles, both uncoated and oleic acid-coated, with the double role of polymerization catalyst and magnetic filler. Oleic acid-coated nanoparticles showed higher catalytic activity than uncoated ones, especially under aerobic conditions. The size of the nanoparticles did not undergo significant changes during the polymerization process. The nanocomposites are magnetically hard with large remanence/saturation ratio, very large coercivity (8–15 kOe at 5 K) and do not display superparamagnetic effects even at RT. The addition of Fe 3+ as a further oxidant allowed to tune the electroconductive properties of the materials, with conductivity ranging from 7.3 ⋅ 10 −5 S/cm to 5.5 ⋅ 10 −3 S/cm.