A facile and green synthesis of MIL-100(Fe) with high-yield and its catalytic performance. (18th October 2017)

• Record Type: Journal Article
• Authors: Han, Le; Qi, Hui; Zhang, Dan; Ye, Gan; Zhou, Wei; Hou, Changmin; Xu, Wei; Sun, Yinyong
• Is Part Of: New journal of chemistry. Volume 41:Number 22(2017)
• Page Start: 13504
• Page End: 13509
• Publication Date: 2017-10-18
• Subjects: Chemistry -- Periodicals; Chimie -- Périodiques; 540
• DOI: 10.1039/c7nj02975f
• Languages: English
• ISSNs: 1144-0546

Abstract

Abstract : MIL-100(Fe) with a high yield of 93% has been successfully synthesized using a facile and green method. Abstract : MIL-100(Fe) is one of the important metal–organic frameworks due to its fascinating physicochemical properties. Generally, MIL-100(Fe) was synthesized under the conditions of adding HF and solvent. Here, we report that MIL-100(Fe) can be facilely synthesized without the addition of solvent and HF. More importantly, this approach can produce MIL-100(Fe) with a high yield of 93%. Additionally, the obtained MIL-100(Fe) exhibited good catalytic performance in the acetalization of benzaldehyde with methanol. This catalyst can still maintain the initial catalytic activity after five cycles.