A pyrene-functionalized foldamer: structural impact and recognition properties supported by donor–acceptor interactions. Issue 88 (23rd October 2017)

• Record Type: Journal Article
• Authors: Aparicio, F.; Faour, L.; Allain, M.; Canevet, D.; Sallé, M.
• Is Part Of: Chemical communications. Volume 53:Issue 88(2017)
• Page Start: 12028
• Page End: 12031
• Publication Date: 2017-10-23
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/c7cc07253h
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : An electroactive and luminescent foldamer proved to have an original hybridized structure and interacts with electron-poor guests. Abstract : An electroactive and luminescent foldamer based on an oligopyridine biscarboxamide skeleton was synthesized and characterised. Its conformation in the solid state proved to be strongly affected by the peripheral pyrene units. The latter also endow the target derivative with recognition abilities toward electron-withdrawing molecules, which allow tuning of the spectroscopic properties of the foldamer.