Synthesis and photophysical and electrochemical properties of three novel Ru(II) complexes. (February 2013)

• Record Type: Journal Article
• Authors: Wang, J. G.; Shang, Y. L.
• Is Part Of: Materials research innovations. Volume 17:Number 2(2013)
• Page Start: 58
• Page End: 61
• Publication Date: 2013-02
• Subjects: Ru(II) complex, -- Extended π-bond conjugation, -- Absorption and emission properties; Materials -- Research -- Periodicals; Matériaux -- Recherche -- Périodiques; 620.1105
• DOI: 10.1179/1433075X12Y.0000000014
• Languages: English
• ISSNs: 1432-8917

Abstract

Abstract : This paper on three heteroleptic {(bpy)2 Ru[2-(perylen-3-yl)-1-H-imidazo[4, 5-f][1, 10]-phenanthroline)]} 2+, {(bpy)2 Ru[2-(pyren-1-yl)-1-H-imidazo[4, 5-f][1, 10]phenanthroline]} 2+ and {(bpy)2 Ru[2-(anthracen-10-yl)-1-H-imidazo[4, 5-f][1, 10]phenanthroline]} 2+ complexes with perylene, pyrene and anthracene appended 1-H-imidazo[4, 5-f][1, 10]-phenanthroline as the diimine ligands is a further demonstration of the effect of extending the diimine ligands' π -system on the absorption and emission properties.