Dynamics of the crystal structure of tin-based type-I clathrates with different degrees of disorder in their cationic frameworks. Issue 40 (6th October 2017)

• Record Type: Journal Article
• Authors: Novikov, V. V.; Pilipenko, K. S.; Matovnikov, A. V.; Mitroshenkov, N. V.; Kornev, B. I.; Likhanov, M. S.; Tyablikov, A. S.; Shevelkov, A. V.
• Is Part Of: Physical chemistry chemical physics. Volume 19:Issue 40(2017)
• Page Start: 27725
• Page End: 27730
• Publication Date: 2017-10-06
• Subjects: Chemistry, Physical and theoretical -- Periodicals; 541.3
• DOI: 10.1039/c7cp05023b
• Languages: English
• ISSNs: 1463-9076

Abstract

Abstract : The temperature dependencies of heat capacity and cubic unit cell parameter for type-I clathrates were obtained to determine the influence of the concentration of vacancies and substituting atoms on the lattice dynamics. Abstract : The temperature dependencies of heat capacity, C P ( T ), and cubic unit cell parameter, a ( T ), were experimentally obtained in the range of 2–300 K for the compounds Sn24 P19.2 I8, Sn20 Zn4 P20.8 I8, and Sn17 Zn7 P22 I8, which belong to a family of type-I clathrates. The experimental data were analyzed in the frames of the Debye–Einstein approximation, further accounting for the contributions of positional disorder in the clathrate frameworks as well as those of defect modes arising from the distribution of guest atoms over unequal in energy but close in space positions inside the framework cages. By fitting the experimental data, the Debye and Einstein characteristic temperatures describing the dynamics of the framework and guest atoms, respectively, were obtained. Their analysis revealed peculiar dependencies of the characteristic temperatures upon the number of substituted zinc atoms and the concentration of vacancies in the framework, which are discussed in this paper.