A two-step method for preparing Li4Ti5O12–graphene as an anode material for lithium-ion hybrid capacitors. Issue 114 (3rd November 2015)

• Record Type: Journal Article
• Authors: Xu, Nansheng; Sun, Xianzhong; Zhang, Xiong; Wang, Kai; Ma, Yanwei
• Is Part Of: RSC advances. Volume 5:Issue 114(2015)
• Page Start: 94361
• Page End: 94368
• Publication Date: 2015-11-03
• Subjects: Chemistry -- Periodicals; 540.5
• DOI: 10.1039/c5ra20168c
• Languages: English
• ISSNs: 2046-2069

Abstract

Abstract : Li4 Ti5 O12 –graphene anode was prepared by a two-step method and applied to a lithium-ion hybrid capacitor which could deliver an energy density of 6.6 W h kg −1 based on the total mass of the whole device. Abstract : Lithium-ion hybrid capacitors (LICs) are expected to fill the gap between lithium-ion batteries and electrochemical supercapacitors. In this paper, we synthesize Li4 Ti5 O12 –graphene (LTO–G) by a two-step method and use it as the anode material in AC/LTO–G Li-ion hybrid capacitors. The LTO–G composite prepared by the two-step method shows the best electrochemical properties in various ways, and delivers a high specific capacity of 194 mA h g −1 at 0.1C, and 90 mA h g −1 at 28.6C. The AC/LTO–G capacitors can perform well between 1 and 2.5 V, and they deliver a reversible capacity of 80 mA h g −1 at 0.1C. The energy density based on the total active material for these capacitors is 15 W h kg −1 at 4000 W kg −1, and 30 W h kg −1 at 1000 W kg −1 . After 10 000 cycles, these capacitors still deliver an energy density higher than 22 W h kg −1 at 1000 W kg −1 . The highest energy density based the total mass of the device is 6.6 W h kg −1 and there is still much room for improvement, indicating that the LTO–G composite is a promising candidate anode material for Li-ion hybrid capacitors.