Changes in microstructure and physical properties of skutterudites after severe plastic deformation. Issue 5 (5th January 2015)

• Record Type: Journal Article
• Authors: Rogl, Gerda; Grytsiv, Andriy; Bursik, Jiri; Horky, Jelena; Anbalagan, Ramakrishnan; Bauer, Ernst; Mallik, Ramesh Chandra; Rogl, Peter; Zehetbauer, Michael
• Is Part Of: Physical chemistry chemical physics. Volume 17:Issue 5(2015)
• Page Start: 3715
• Page End: 3722
• Publication Date: 2015-01-05
• Subjects: Chemistry, Physical and theoretical -- Periodicals; 541.3
• DOI: 10.1039/c4cp05230g
• Languages: English
• ISSNs: 1463-9076

Abstract

Abstract : Although electrical resistivity after HPT of DD0.68 Fe3 CoSb12 is higher, the lower thermal conductivity overcompensates resulting in a 20% higher ZT. Abstract : The best p-type skutterudites with ZT > 1.1 so far are didymium (DD) filled, Fe/Co substituted, Sb-based skutterudites. DD0.68 Fe3 CoSb12 was prepared using an annealing–reacting–melting–quenching technique followed by ball milling and hot pressing. After severe plastic deformation via high-pressure torsion (HPT), no phase changes but particular structural variations were achieved, leading to modified transport properties with higher ZT values. Although after measurement-induced heating some of the HPT induced defects were annealed out, a still attractive ZT-value was preserved. In this paper we focus on explanations for these changes via TEM investigations, Raman spectroscopy and texture measurements. The grain sizes and dislocation densities, evaluated from TEM images, showed that (i) the majority of cracks generated during high-pressure torsion are healed during annealing, leaving only small pores, that (ii) the grains have grown, and that (iii) the dislocation density is decreased. While Raman spectra indicate that after HPT processing and annealing the vibration modes related to the shorter Sb–Sb bonds in the Sb4 rings are more affected than those related to the longer Sb–Sb bonds, almost no visible changes were observed in the pole intensity and/or orientation.