Rheological characterization of liquid-to-solid transitions in bulk polyelectrolyte complexes. Issue 40 (27th September 2017)

• Record Type: Journal Article
• Authors: Liu, Yalin; Momani, Brian; Winter, H. Henning; Perry, Sarah L.
• Is Part Of: Soft matter. Volume 13:Issue 40(2017)
• Page Start: 7332
• Page End: 7340
• Publication Date: 2017-09-27
• Subjects: Soft condensed matter -- Periodicals; 530.413
• DOI: 10.1039/c7sm01285c
• Languages: English
• ISSNs: 1744-683X

Abstract

Abstract : We use linear viscoelasticity measurements to characterize the salt-driven liquid-to-solid transition of 'saloplastic' polyelectrolyte complexes. Abstract : Polyelectrolyte complexation has long been known to result in both liquid and solid complexes. However, the exact nature of the liquid-to-solid transition remains an open question. We have used rheology to explain this phenomenon for the model system of poly(4-styrenesulfonic acid, sodium salt) (PSS) and poly(diallyldimethyl ammonium chloride) (PDADMAC) in the presence of potassium bromide (KBr). The use of a time-salt superposition allows for a detailed analysis of changes in the linear viscoelastic response for both liquid complex coacervates and solid polyelectrolyte complexes as a function of salt concentration, and facilitates unambiguous determination of the mechanism for this phase transition. Decreasing salt concentration, and the commensurate decrease in the water content of PSS/PDADMAC/KBr complexes is shown to lead to the formation of a physical gel due to the development of a network with trapped electrostatic crosslinks that percolates the sample at a critical salt concentration.