Vapor pressures, thermodynamic stability, and fluorescence properties of three 2, 6-alkyl naphthalenes. (March 2016)

• Record Type: Journal Article
• Authors: Santos, Ana Filipa L.O.M.; Oliveira, Juliana A.S.A.; Ribeiro da Silva, Maria D.M.C.; Monte, Manuel J.S.
• Is Part Of: Chemosphere. Volume 146(2016)
• Page Start: 173
• Page End: 181
• Publication Date: 2016-03
• Subjects: Naphthalene derivatives -- Vapor pressure -- Enthalpy of formation -- Gibbs energy of formation -- Fluorescence; Pollution -- Periodicals; Pollution -- Physiological effect -- Periodicals; Environmental sciences -- Periodicals; Atmospheric chemistry -- Periodicals; 551.511
• DOI: 10.1016/j.chemosphere.2015.11.114
• Languages: English
• ISSNs: 0045-6535

Abstract

Abstract: This work reports the experimental determination of relevant thermodynamic properties and the characterization of luminescence properties of the following polycyclic aromatic hydrocarbons (PAHs): 2, 6-diethylnaphthalene, 2, 6-diisopropylnaphthalene and 2, 6-di- tert -butylnaphthalene. The standard ( p o = 0.1 MPa) molar enthalpies of combustion, Δ c H m o, of the three compounds were determined using static bomb combustion calorimetry. The vapor pressures of the crystalline phase of 2, 6-diisopropylnaphthalene and 2, 6-di- tert -butylnaphthalene were measured at different temperatures using the Knudsen effusion method and the vapor pressures of both liquid and crystalline phases of 2, 6-diethylnaphthalene were measured by means of a static method. The temperatures and the molar enthalpies of fusion of the three compounds were determined using differential scanning calorimetry. The gas-phase molar heat capacities and absolute entropies of the three 2, 6-dialkylnaphthalenes studied were determined computationally. The thermodynamic stability of the compounds in both the crystalline and gaseous phases was evaluated by the determination of the Gibbs energies of formation and compared with the ones reported in the literature for 2, 6-dimethylnaphthalene. From fluorescence spectroscopy measurements, the optical properties of the compounds studied and of naphthalene were evaluated in solution and in the solid state. Graphical abstract: Highlights: Thermodynamic and optical properties of 2, 6-dialkyl naphthalenes were determined. Vapor pressures of the compounds were measured at different temperatures. Thermodynamic stabilities of the compounds were evaluated from Δ f G m o . Quantum yields in the solid state and in solution were determined.