Enhancing the output current of a CdTe solar cell via a CN-free hydrocarbon luminescent down-shifting fluorophore with intramolecular energy transfer and restricted internal rotation characteristics. Issue 4 (13th February 2015)

• Record Type: Journal Article
• Authors: Li, Yilin; Olsen, Joseph; Dong, Wen-Ji
• Is Part Of: Photochemical & photobiological sciences. Volume 14:Issue 4(2015:Apr.)
• Page Start: 833
• Page End: 841
• Publication Date: 2015-02-13
• Subjects: Photochemistry -- Periodicals; Photobiology -- Periodicals; 541.35
• DOI: 10.1039/c4pp00480a
• Languages: English
• ISSNs: 1474-905X

Abstract

Abstract : A novel CN-free hydrocarbon as a luminescent down-shifting fluorophore that enhances the output short circuit current density of a CdTe solar cell by as high as 3.30 ± 0.31%. Abstract : A CN-free hydrocarbon fluorophore (Perylene-TPE ) was synthesized as a new luminescent down-shifting (LDS) material. Its photophysical properties in both the solution state and the solid state were studied. The unity fluorescence quantum yield ofPerylene-TPE observed in its solid state is considered to be from the characteristics of intramolecular energy transfer (IET) and restricted internal rotation (RIR). This is supported by the results from theoretical calculations and spectroscopic measurements. For the photovoltaic application ofPerylene-TPE, a theoretical modeling study suggests that using the LDS film ofPerylene-TPE may increase the output short circuit current density ( J sc ) of a CdTe solar cell by 2.95%, enhance the spectral response of a CdTe solar cell at 400 nm by 41%, and shift the incident solar photon distribution from short-wavelength (<500 nm) to long-wavelength (>500 nm). Experimentally, placing a LDS film ofPerylene-TPE on a CdTe solar cell can enhance its output J sc by as high as 3.30 ± 0.31%, which is comparable to the current commercially available LDS material – Y083 (3.28% ± 0.37%).