Crystal morphology, dispersing stability and dyeing property of the disperse dye based on benzisothiazole. Issue 6 (3rd November 2014)

• Record Type: Journal Article
• Authors: Li, Min; Song, Kaili; Xie, Kongliang; Hou, Aiqin
• Is Part Of: Pigment & resin technology. Volume 43:Issue 6(2014)
• Page Start: 365
• Page End: 370
• Publication Date: 2014-11-03
• Subjects: Dyes -- Dispersions -- Crystal morphology -- Dyeing -- Polyester; Protective coatings -- Periodicals; 667.62305
• DOI: 10.1108/PRT-10-2013-0099
• Languages: English
• ISSNs: 0369-9420

Abstract

Abstract : Purpose: The purpose of this paper is to synthesise a disperse dye based on benzisothiazole and to characterise its crystal morphology, dispersing stability, to study the relationship between the chemical structure and the dyeing property of the dye. Design/methodology/approach: The disperse dye based on benzisothiazole, 3-(3-methyl-4-N-ethyl-N-benzyl-phenyldiazenyl)-5-nitro-2, 1-benzisothiazoles, was synthesized. The disperse dye based on benzisothiazole, 3-(3-methyl-4-N-ethyl-N-benzyl-phenyldiazenyl)-5-nitro-2, 1-benzisothiazoles, was synthesised. The chemical structure of the dye obtained was characterised by infrared spectrum Fourier transform infrared spectroscopy and nuclear magnetic resonance (1HNMR), and the crystal morphology was observed by Field Emission Scanning Electron Microscopy. Sodium salt of polycondensated naphthalenesulphonic acid (dispersing agent sodium salt of polycondensated naphthalenesulphonic acid [MF]) and a sulphonated amino polyether (anionic surfactant B600) were employed to grind and disperse the dye crystals. The dispersion property of the dye particles was characterised. Dyeing property of the dispersion system was also studied. Findings: The dye formed spherical crystals that were made up of a large number of acicular crystals similar to spherical chrysanthemum. The crystals had warping crystal centres inside the spheres. The particle sizes of the dispersion with the mixture of B600 and MF had an uniform distribution and were smaller than that of the dispersion with only single dispersing agent MF. Dyeing with the dispersion system had an excellent reproducibility under alkalinic condition. Practical implications: An alkalinic dyeing method for poly(ethylene terephthalate) (PET) with disperse dyes as a cleaner wet process had been developed. Such a process combined pretreatment and dyeing process using the alkali-stable disperse dyes and reduced the consumption of water and energy and improved production efficiency. Originality/value: The crystal morphology, dispersion and dyeing properties of the synthesised disperse dye for dyeing PET fabric under alkalinic condition were discussed. This disperse dye has an important potential application in alkalinic dyeing method.