A novel metalloporphyrin-based conjugated microporous polymer for capture and conversion of CO2. Issue 40 (2nd April 2015)

• Record Type: Journal Article
• Authors: Sheng, Xingfeng; Guo, Hongchen; Qin, Yusheng; Wang, Xianhong; Wang, Fosong
• Is Part Of: RSC advances. Volume 5:Issue 40(2015)
• Page Start: 31664
• Page End: 31669
• Publication Date: 2015-04-02
• Subjects: Chemistry -- Periodicals; 540.5
• DOI: 10.1039/c4ra16675b
• Languages: English
• ISSNs: 2046-2069

Abstract

Abstract : A novel conjugated microporous polymer was solvothermally synthesized, which had high BET specific surface area and pore volume, and displayed excellent capacity to capture carbon dioxide and good catalytic activity for cyclic carbonate synthesis. Abstract : A novel conjugated microporous polymer was solvothermally synthesized using an aluminum porphyrin as a main building block, which had a high Brunauer–Emmett–Teller specific surface area up to 839 m 2 g −1 and a pore volume of 2.14 cm 3 g −1 . The polymer displayed excellent capacity to capture carbon dioxide (4.3 wt%) at 273 K and 1 bar, and good catalytic activity for cyclic carbonate synthesis with TOF up to 364 h −1 .