Nickel cobaltite nanograss grown around porous carbon nanotube-wrapped stainless steel wire mesh as a flexible electrode for high-performance supercapacitor application. (10th November 2015)

• Record Type: Journal Article
• Authors: Wu, Mao-Sung; Zheng, Zhi-Bin; Lai, Yu-Sheng; Jow, Jiin-Jiang
• Is Part Of: Electrochimica acta. Volume 182(2015)
• Page Start: 31
• Page End: 38
• Publication Date: 2015-11-10
• Subjects: Carbon nanotubes -- Porous film -- Nanograss -- Hydrothermal method -- Supercapacitor; Electrochemistry -- Periodicals; Electrochemistry, Industrial -- Periodicals; 541.37
• DOI: 10.1016/j.electacta.2015.09.049
• Languages: English
• ISSNs: 0013-4686

Abstract

Graphical abstract: Nickel cobaltite nanograss with bimodal pore size distribution is grown around the carbon nanotube-wrapped stainless steel wire mesh as a high capacitance and stable electrode for high-performance and flexible supercapacitors. Highlights: NiCo2 O4 nanograss with bimodal pore size distribution is hydrothermally prepared. Carbon nanotubes (CNTs) wrap around stainless steel (SS) wire mesh as a scaffold. NiCo2 O4 grown on CNT-wrapped SS mesh shows excellent capacitive performance. Porous CNT layer allows for rapid transport of electron and electrolyte. Abstract: Nickel cobaltite nanograss with bimodal pore size distribution (small and large mesopores) is grown on various electrode substrates by one-pot hydrothermal synthesis. The small pores (<5 nm) in the nanograss of individual nanorods contribute to large surface area, while the large pore channels (>20 nm) between nanorods offer fast transport paths for electrolyte. Carbon nanotubes (CNTs) with high electrical conductivity wrap around stainless steel (SS) wire mesh by electrophoresis as an electrode scaffold for supporting the nickel cobaltite nanograss. This unique electrode configuration turns out to have great benefits for the development of supercapacitors. The specific capacitance of nickel cobaltite grown around CNT-wrapped SS wire mesh reaches 1223 and 1070 F g −1 at current densities of 1 and 50 A g −1, respectively. CNT-wrapped SS wire mesh affords porous and conductive networks underneath the nanograss for rapid transport of electron and electrolyte. Flexible CNTs connect the nanorods to mitigate the contact resistance and the volume expansion during cycling test. Thus, this tailored electrode can significantly reduce the ohmic resistance, charge-transfer resistance, and diffusive impedance, leading to high specific capacitance, prominent rate performance, and good cycle-life stability.