A novel fabrication of a polymeric ionic liquid hybrid film modified electrode and its successful application to the electrogeneration of a superoxide anion in aqueous media. Issue 16 (26th January 2015)

• Record Type: Journal Article
• Authors: Nilushika, Dilani; Awad, Mohamed I.; Saleh, Mahmoud M.; Okajima, Takeyoshi; Mao, Lanqun; Ohsaka, Takeo
• Is Part Of: Chemical communications. Volume 51:Issue 16(2015)
• Page Start: 3343
• Page End: 3346
• Publication Date: 2015-01-26
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/c4cc08410a
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : An ionene polymer-ionic liquid hybrid was fabricated by electro-oxidative polymerization of N, N -dimethylaniline in [MPP] + [N(Tf)2 ] −, which can be applied for the electrogeneration of a superoxide anion in aqueous media. Abstract : A novel polymeric ionic liquid hybrid film-modified electrode, in which the electrode surface is coated with a hydrophobic hybrid material composed of an ionene polymer with quaternary ammonium sites in its polymeric backbone and ionic liquids, was fabricated by electropolymerization of N, N -dimethylaniline in a hydrophobic ionic liquid, which can be applied for the electrogeneration of a superoxide anion via one-electron reduction of O2 in aqueous media.