Efficient electrosynthesis of phosphinic amides via oxidative cross-coupling between N–H/P–H. Issue 20 (18th September 2017)

• Record Type: Journal Article
• Authors: Wang, Yukang; Qian, Peng; Su, Ji-Hu; Li, Yanan; Bi, Meixiang; Zha, Zhenggen; Wang, Zhiyong
• Is Part Of: Green chemistry. Volume 19:Issue 20(2017)
• Page Start: 4769
• Page End: 4773
• Publication Date: 2017-09-18
• Subjects: Environmental chemistry -- Industrial applications -- Periodicals; Environmental management -- Periodicals; 660
• DOI: 10.1039/c7gc01989k
• Languages: English
• ISSNs: 1463-9262

Abstract

Abstract : A facile and efficient approach to phosphinic amides was developed from diarylphosphine oxides and amines via electrosynthesis. A variety of phosphinic amides were obtained in one step with good to excellent yields under mild and metal-free conditions. The corresponding mechanism was investigated. Abstract : A facile and efficient approach to phosphinic amides was developed from diarylphosphine oxides and amines via electrosynthesis. A variety of phosphinic amides were obtained in one step with good to excellent yields under mild and metal-free conditions. The corresponding mechanism was investigated.