[Hyp-Au-Sn9(Hyp)3-Au-Sn9(Hyp)3-Au-Hyp]−: the longest intermetalloid chain compound of tin. Issue 82 (2nd October 2017)

• Record Type: Journal Article
• Authors: Binder, Mareike; Schrenk, Claudio; Block, Theresa; Pöttgen, Rainer; Schnepf, Andreas
• Is Part Of: Chemical communications. Volume 53:Issue 82(2017)
• Page Start: 11314
• Page End: 11317
• Publication Date: 2017-10-02
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/c7cc07029b
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : The reaction of the metalloid tin cluster [Sn10 (Hyp)4 ] 2− with (Ph3 P)Au-SHyp (Hyp = Si(SiMe3 )3 ) gave an intermetalloid cluster [Au3 Sn18 (Hyp)8 ] − 1, which is the longest intermetalloid chain compound of tin to date. Abstract : The reaction of the metalloid tin cluster [Sn10 (Hyp)4 ] 2− with (Ph3 P)Au-SHyp (Hyp = Si(SiMe3 )3 ) gave an intermetalloid cluster [Au3 Sn18 (Hyp)8 ] − 1, which is the longest intermetalloid chain compound of tin to date.1 shows a structural resemblance to binary AuSn phases, which is expected for intermetalloid clusters.