A EuIII‐MOF with Bis(2‐carboxyethyl)isocyanurate for Luminescence Sensing of Fe3+ and SCN– Ions. Issue 17 (21st August 2017)

• Record Type: Journal Article
• Authors: Zhang, Yanan; Zhang, Peng; Yin, Haiju; Cheng, Jing; Kang, Yifan
• Is Part Of: Zeitschrift für anorganische und allgemeine Chemie. Volume 643:Issue 17(2017)
• Page Start: 1126
• Page End: 1130
• Publication Date: 2017-08-21
• Subjects: Lanthanide‐MOF -- Fluorescent probes -- Bis(2‐carboxyethyl)isocyanurate -- Europium; Chemistry, Inorganic -- Periodicals; Chemistry -- Periodicals; 540
• DOI: 10.1002/zaac.201700175
• Languages: English
• ISSNs: 0044-2313

Abstract

Abstract : The water‐stable 3D lanthanide‐organic framework ( Ln ‐MOF) {[Eu(bci)(H2 O)]· 2H2 O} n (1 ) [H2 bci = bis(2‐carboxyethyl)isocyanurate] was synthesized under hydrothermal conditions. Compound1 ‐Eu exhibits a 3D open‐framework connected by Eu–(μ‐O)2 –Eu chains and bci ligands. Meanwhile, 1 ‐Eu exhibits highly efficient luminescent sensing for environmentally relevant Fe 3+ and SCN – ions through luminescence quenching. These results indicated that it could be utilized as a multi‐responsive luminescence sensor. Abstract :