Activation of the P–H bond by a frustrated Lewis pair and its application in catalytic Z-selective hydrophosphonylation of terminal ynones. Issue 79 (26th July 2017)
- Record Type:
- Journal Article
- Title:
- Activation of the P–H bond by a frustrated Lewis pair and its application in catalytic Z-selective hydrophosphonylation of terminal ynones. Issue 79 (26th July 2017)
- Main Title:
- Activation of the P–H bond by a frustrated Lewis pair and its application in catalytic Z-selective hydrophosphonylation of terminal ynones
- Authors:
- Liu, Yizhen
Fan, Xiaoting
Li, Zhen Hua
Wang, Huadong - Abstract:
- Abstract : Z -Selective hydrophosphonylation of terminal ynones was achieved by employing a frustrated Lewis pair catalyst. Abstract : The frustrated Lewis pair (FLP) comprised of B(C6 F5 )3 and 1, 2, 2, 6, 6-pentamethylpiperidine (PMP) can efficiently catalyze Z -selective hydrophosphonylation of terminal ynones with a Z / E selectivity of up to 20 : 1. Mechanistic studies suggest that the trans arrangement of the phosphite nucleophilic attack and hydrogen bond formation on the alkyne moiety is responsible for the observed Z -selectivity.
- Is Part Of:
- Chemical communications. Volume 53:Issue 79(2017)
- Journal:
- Chemical communications
- Issue:
- Volume 53:Issue 79(2017)
- Issue Display:
- Volume 53, Issue 79 (2017)
- Year:
- 2017
- Volume:
- 53
- Issue:
- 79
- Issue Sort Value:
- 2017-0053-0079-0000
- Page Start:
- 10890
- Page End:
- 10893
- Publication Date:
- 2017-07-26
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/c7cc05028c ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 4719.xml