Organic and Organometallic Derivatives of Propargylallene: Syntheses, Structures, Reactivity and Rearrangements. Issue 22 (21st May 2013)

• Record Type: Journal Article
• Authors: McGlinchey, Michael J.; Hopf, Henning
• Is Part Of: European journal of organic chemistry. Issue 22(2013)
• Page Start: 4705
• Page End: 4728
• Publication Date: 2013-05-21
• Subjects: Allenes -- Alkynes -- Ther­molyses -- Molecular rearrangements -- Noble­ metal catalysis -- Cycloaddition; Chemistry, Organic -- Periodicals; Organic compounds -- Synthesis -- Periodicals; Bioorganic chemistry -- Periodicals; Chemistry, Physical organic -- Periodicals; 547
• DOI: 10.1002/ejoc.201300250
• Languages: English
• ISSNs: 1434-193X

Abstract

Abstract: Propargylallenes offer the varied reactivity patterns of two different multiple bond linkages either separately or in concert. Their syntheses, structures, rearrangement mechanisms and synthetic utility are reviewed, together with their behaviour when treated with transition‐metal reagents such as gold(I), silver(I), platinum metals or metal carbonyls. Abstract : Propargylallenes offer varied reactivity patterns arising from the presence of two different multiple bond linkages, either separately or in concert. We review their syntheses, structures, rearrangement mechanisms and synthetic utility, together with their behaviour on treatment with transition‐metal reagents such as gold(I), silver(I), platinum metals or metal carbonyls.