CS and CN bond formation via Mn-promoted oxidative cascade reaction: Synthesis of C3-sulfenated indoles. Issue 43 (26th October 2017)
- Record Type:
- Journal Article
- Title:
- CS and CN bond formation via Mn-promoted oxidative cascade reaction: Synthesis of C3-sulfenated indoles. Issue 43 (26th October 2017)
- Main Title:
- CS and CN bond formation via Mn-promoted oxidative cascade reaction: Synthesis of C3-sulfenated indoles
- Authors:
- He, Lin
Li, Xianwei - Abstract:
- Abstract: Thioethers are of synthetic value in pharmaceutical molecules and nature products, herein, we report an oxidative cascade reaction that delivers multiple substituted indole thioethers with great efficiency. This transformation utilized ortho -azido aromatic alkynes as the substrates, and sulfonyl hydrazides as the sulfenation reagent promoted by Mn(III) catalyst. Notably, great functional group tolerance, in combination with nitrogen and water as the byproducts, highlighted the sustainable chemistry of this protocol. Graphical abstract:
- Is Part Of:
- Tetrahedron. Volume 73:Issue 43(2017)
- Journal:
- Tetrahedron
- Issue:
- Volume 73:Issue 43(2017)
- Issue Display:
- Volume 73, Issue 43 (2017)
- Year:
- 2017
- Volume:
- 73
- Issue:
- 43
- Issue Sort Value:
- 2017-0073-0043-0000
- Page Start:
- 6138
- Page End:
- 6145
- Publication Date:
- 2017-10-26
- Subjects:
- Oxidative cascade reaction -- Thioether -- Indoles -- Azido -- Molecular oxygen
Chemistry, Organic -- Periodicals
547.005 - Journal URLs:
- http://www.elsevier.com/journals ↗
- DOI:
- 10.1016/j.tet.2017.09.003 ↗
- Languages:
- English
- ISSNs:
- 0040-4020
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 8796.850000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 4709.xml