ChemInform Abstract: Trifluoromethoxylation of Arenes: Synthesis of ortho‐Trifluoromethoxylated Aniline Derivatives by OCF3 Migration. Issue 19 (May 2015)

• Record Type: Journal Article
• Authors: Hojczyk, Katarzyna N.; Feng, Pengju; Zhan, Chengbo; Ngai, Ming‐Yu
• Is Part Of: ChemInform. Volume 46:Issue 19(2015)
• Page Start: no
• Page End: no
• Publication Date: 2015-05
• Subjects: amines (benzene compounds) -- phenol ethers -- rearrangements -- catalysis, phase‐transfer catalysis; Chemistry -- Abstracts -- Periodicals; 540.5
• DOI: 10.1002/chin.201519089
• Languages: English
• ISSNs: 0931-7597

Abstract

Abstract: N‐protected N‐arylhydroxylamines are initially O‐trifluoromethylated prior to a thermally induced migration of the CF3 ‐O‐group from the amino function to the ortho‐position of the attached arene.