ChemInform Abstract: Accessing 2‐(Hetero)arylmethyl‐, ‐allyl‐, and ‐propargyl‐2, 1‐borazaronaphthalenes: Palladium‐Catalyzed Cross‐Couplings of 2‐(Chloromethyl)‐2, 1‐borazaronaphthalenes. Issue 19 (May 2015)

• Record Type: Journal Article
• Authors: Molander, Gary A.; Amani, Javad; Wisniewski, Steven R.
• Is Part Of: ChemInform. Volume 46:Issue 19(2015)
• Page Start: no
• Page End: no
• Publication Date: 2015-05
• Subjects: organo‐boron compounds -- C‐C bond formation; Chemistry -- Abstracts -- Periodicals; 540.5
• DOI: 10.1002/chin.201519238
• Languages: English
• ISSNs: 0931-7597

Abstract

Abstract: The cross‐coupling reactions of 2‐(chloromethyl)‐2, 1‐borazaronaphthalene with potassium (hetero)aryl‐ and alkenyltrifluoroborates as well as terminal alkynes provides access to a variety of novel azaborines, allowing a library of pseudobenzylic substituted azaborines to be prepared from a common starting material.