Fe-Catalyzed insertion of fluoromethylcarbenes generated from sulfonium salts into X–H bonds (X = Si, C, P). Issue 10 (27th June 2017)
- Record Type:
- Journal Article
- Title:
- Fe-Catalyzed insertion of fluoromethylcarbenes generated from sulfonium salts into X–H bonds (X = Si, C, P). Issue 10 (27th June 2017)
- Main Title:
- Fe-Catalyzed insertion of fluoromethylcarbenes generated from sulfonium salts into X–H bonds (X = Si, C, P)
- Authors:
- Duan, Yaya
Lin, Jin-Hong
Xiao, Ji-Chang
Gu, Yu-Cheng - Abstract:
- Abstract : The Fe-catalyzed insertion of fluoromethylcarbenes including trifluoromethylcarbene and difluoromethylcarbene into X–H (X = Si, C and P) bonds is described. Abstract : The Fe-catalyzed insertion of fluoromethylcarbenes including trifluoromethylcarbene and difluoromethylcarbene generated in situ from sulfonium salts (Ph2 S + CH2 CF3 − OTf and Ph2 S + CH2 CF2 H − OTf) into X–H (X = Si, C and P) bonds is described. The insertion of both carbenes into the Si–H bond occurred smoothly, and trifluoromethylcarbene could also insert into C–H and P–H bonds.
- Is Part Of:
- Organic chemistry frontiers. Volume 4:Issue 10(2017)
- Journal:
- Organic chemistry frontiers
- Issue:
- Volume 4:Issue 10(2017)
- Issue Display:
- Volume 4, Issue 10 (2017)
- Year:
- 2017
- Volume:
- 4
- Issue:
- 10
- Issue Sort Value:
- 2017-0004-0010-0000
- Page Start:
- 1917
- Page End:
- 1920
- Publication Date:
- 2017-06-27
- Subjects:
- Chemistry, Organic -- Periodicals
547.005 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/qo#!recentarticles&all ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/c7qo00430c ↗
- Languages:
- English
- ISSNs:
- 2052-4110
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 6287.121000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 4655.xml