Impact of aerosol microphysical properties on mass scattering cross sections. (October 2017)

• Record Type: Journal Article
• Authors: Obiso, V.; Pandolfi, M.; Ealo, M.; Jorba, O.
• Is Part Of: Journal of aerosol science. Volume 112(2017)
• Page Start: 68
• Page End: 82
• Publication Date: 2017-10
• Subjects: Aerosol microphysical properties -- Aerosol optical properties -- Aerosol scattering spectral analysis -- Aerosol source scattering observations -- Constraints on particle microphysical properties; Aerosols -- Periodicals; Aerosols -- Periodicals; Aérosols -- Périodiques; 541.34515
• DOI: 10.1016/j.jaerosci.2017.03.001
• Languages: English
• ISSNs: 0021-8502

Abstract

Abstract: We assessed the sensitivity of simulated mass scattering cross sections ( α λ sca ) of three aerosol species to perturbed particle microphysical properties and derived constraints on these microphysical properties, suitable for the north-western Mediterranean basin, from a comparison between code calculations and observations. In detail, we calculated α λ sca of mineral dust, organic carbon and sulfate at three wavelengths in the visible range ( λ 1 = 0, 450 μ m ; λ 2 = 0, 525 μ m ; λ 3 = 0, 635 μ m ) with a T-matrix optical code, considering ±20% perturbations on size distribution, refractive index and mass density (respect to reference values mainly taken from the OPAC database), and spheroids with two different axial ratios as shape perturbations (reference shape: sphere). Then, we compared the simulation results with a set of observed α λ sca of mineral dust, aged organics and ammonium sulfate sources, available at the same three wavelengths of the code calculations. These observations, provided by the Institute of Environmental Assessment and Water Research (IDAEA-CSIC), have been derived through Multilinear Regression (MLR) analysis from measurements of aerosol mass concentrations and optical properties, collected during a 4-year campaign at the Montseny regional background station (Spain) and representative of the north-western Mediterranean basin. We observed quite different impacts of the microphysical perturbations on α λ sca values and spectral dependence for different aerosol species, due mainly to the different size of the particles respect to the visible wavelengths. Moreover, by means of a compatibility test on best fit parameters, we constrained the mineral dust log-normal size distribution to a geometric radius and a standard deviation of r g = 3, 583 · 10 − 1 μ m and σ g = 1, 600, respectively (effective radius: r eff = 6, 221 · 10 − 1 μ m ), the organic carbon log-normal size distribution parameters to r g = 2, 544 · 10 − 2 μ m and σ g = 1, 760 ( r eff = 5, 656 · 10 − 2 μ m ), the organic carbon real refractive index to n R = ( 1, 576 ; 1, 576 ; 1, 576 ) at ( λ 1 ; λ 2 ; λ 3 ), the sulfate log-normal size distribution parameters to r g = 8, 340 · 10 − 2 μ m and σ g = 1, 624 ( r eff = 1, 501 · 10 − 1 μ m ) and the sulfate real refractive index to n R = ( 1, 547 ; 1, 545 ; 1, 543 ) at ( λ 1 ; λ 2 ; λ 3 ), in the north-western Mediterranean basin. Regarding the other perturbed microphysical properties, we found the reference prescriptions to be suitable for this geographical region, according to the same analysis procedure. Abstract : Highlights: Aerosol scattering simulated under variable microphysical properties (visible range). Sensitivity of scattering to microphysical properties depends on particle mean size. Scattering spectral dependence is slightly affected by microphysical assumptions. Size distribution and real refractive index have strongest impact on scattering. Comparison with source scattering observations constrained microphysical assumptions.