Orientated graphene oxide/Nafion ultra-thin layer coated composite membranes for vanadium redox flow battery. (24th August 2017)

• Record Type: Journal Article
• Authors: Su, Lei; Zhang, Daishuang; Peng, Sangshan; Wu, Xuemei; Luo, Yongliang; He, Gaohong
• Is Part Of: International journal of hydrogen energy. Volume 42:Number 34(2017)
• Page Start: 21806
• Page End: 21816
• Publication Date: 2017-08-24
• Subjects: Orientated graphene oxide -- Nafion -- Spin coating -- Composite membranes -- Vanadium redox flow battery; Hydrogen as fuel -- Periodicals; Hydrogène (Combustible) -- Périodiques; Hydrogen as fuel; Periodicals; 665.81
• DOI: 10.1016/j.ijhydene.2017.07.049
• Languages: English
• ISSNs: 0360-3199

Abstract

Abstract: Graphene oxide (GO)/Nafion composite membranes, with orientated GO nanosheets in parallel to the surface of the ultra-thin coating layer (400–440 nm), are prepared by spin coating method and evidenced by electron microscopy analysis. Orientation of GO maximizes the vanadium ions barrier effect of GO. The GO/Nafion membrane (M-2) achieves lower vanadium ion permeability (8.2 × 10 −8 cm 2 min −1, only 2.64% of the pristine Nafion membrane), and higher coulombic efficiency and energy efficiency (92.9–98.8% and 81.5–88.4%, respectively) comparing with the pristine Nafion membrane (73.3–90.5% and 68.9–79.1%, respectively) at current densities of 20–100 mA cm −2 . With the design of orientated GO nanosheets and ultra-thin GO/Nafion coating layer, good balance between vanadium crossover suppression and protons conduction retention is achieved. M-2 exhibits excellent battery performances over 200 charge-discharge cycles. The capacity decay rate is about 0.23% per cycle, much lower than those assembled with Nafion 212 (0.40% per cycle) and the recast Nafion membrane (0.44% per cycle). Spin coating with water suspensor leads to uniform dispersion of GO and good binding between GO/Nafion coating layer and substrate Nafion membrane. Therefore, the composite membrane could be reinforced by GO and keep integration even with 200 cycles operation. Highlights: Orientated GO/Nafion ultra-thin layer (440 nm) coated composite membrane is prepared. Balance of vanadium crossover and H + conduction by GO orientation in ultra-thin layer. GO/Nafion exhibits lower capacity decay rate (0.23%) than Nafion 212 over 200 cycles.