High Efficiency Photocatalytic Water Splitting Using 2D α‐Fe2O3/g‐C3N4 Z‐Scheme Catalysts. Issue 17 (8th May 2017)

• Record Type: Journal Article
• Authors: She, Xiaojie; Wu, Jingjie; Xu, Hui; Zhong, Jun; Wang, Yan; Song, Yanhua; Nie, Kaiqi; Liu, Yang; Yang, Yingchao; Rodrigues, Marco‐Tulio F.; Vajtai, Robert; Lou, Jun; Du, Daolin; Li, Huaming; Ajayan, Pulickel M.
• Is Part Of: Advanced energy materials. Volume 7:Issue 17(2017)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2017-05-08
• Subjects: 2D hybrids -- hydrogen evolution -- photocatalysis -- water splitting -- Z‐scheme; Energy harvesting -- Materials -- Periodicals; Energy conversion -- Materials -- Periodicals; Energy storage -- Materials -- Periodicals; Photovoltaics -- Periodicals; Fuel cells -- Periodicals; Thermoelectric materials -- Periodicals; 621.31
• DOI: 10.1002/aenm.201700025
• Languages: English
• ISSNs: 1614-6832

Abstract

Abstract : Photocatalysis is the most promising method for achieving artificial photosynthesis, but a bottleneck is encountered in finding materials that could efficiently promote the water splitting reaction. The nontoxicity, low cost, and versatility of photocatalysts make them especially attractive for this application. This study demonstrates that small amounts of α‐Fe2 O3 nanosheets can actively promote exfoliation of g‐C3 N4, producing 2D hybrid that exhibits tight interfaces and an all‐solid‐state Z‐scheme junction. These nanostructured hybrids present a high H2 evolution rate >3 × 10 4 µmol g ‐1 h ‐1 and external quantum efficiency of 44.35% at λ = 420 nm, the highest value so far reported among the family of g‐C3 N4 photocatalysts. Besides effectively suppressing the recombination of electron–hole pairs, this Z‐scheme junction also exhibits activity toward overall water splitting without any sacrificial donor. The proposed synthetic route for controlled production of 2D g‐C3 N4 ‐based structures provides a scalable alternative toward the development of highly efficient and active photocatalysts. Abstract : A Z‐scheme catalyst is considered as a promising material for photocatalytic water splitting. α‐Fe2 O3 can actively promote exfoliation of g‐C3 N4, producing two‐dimensional Z‐scheme α‐Fe2 O3 /2D g‐C3 N4 . Hybrids show a high H2 evolution rate of 31 400 μmol g −1 h −1 and significantly enhanced quantum efficiency up to 44.35% (λ = 420 nm), which is the highest value so far reported for g‐C3 N4 ‐based photocatalysts.