Effects of Doping Methods and Kinetic Relevance of N and O Atomic Co-Functionalization on Carbon Electrode for V(IV)/V(V) Redox Reactions in Vanadium Redox Flow Battery. (10th August 2017)

• Record Type: Journal Article
• Authors: Kim, Jiyeon; Lim, Hyebin; Jyoung, Jy-Young; Lee, Eun-Sook; Yi, Jung S.; Lee, Doohwan
• Is Part Of: Electrochimica acta. Volume 245(2017)
• Page Start: 724
• Page End: 733
• Publication Date: 2017-08-10
• Subjects: Vanadium Redox Flow Battery -- Carbon Electrode -- Surface Functionalization -- Nitrogen Doping -- Oxygen Doping; Electrochemistry -- Periodicals; Electrochemistry, Industrial -- Periodicals; 541.37
• DOI: 10.1016/j.electacta.2017.06.008
• Languages: English
• ISSNs: 0013-4686

Abstract

Highlights: N and O atomic co-doping of carbon electrode was conducted by various methods. Collective analysis was conducted for the electrode performance with the doped groups. Pyrrolic-N and −OH groups were identified as the most kinetically relevant surface species. High electrocatalytic performance of the electrode was demonstrated in a VRFB cell. Abstract: In this study, electrocatalytic effects of nitrogen (N) and oxygen (O) atomic co-doping on carbon electrode are studied for vanadium redox flow battery (VRFB). The N and O co-functionalized graphite felt (GF) electrodes are prepared by two different synthesis routes: (i) impregnation of urea or melamine on the pristine-GF followed by reactions at high temperatures (batch process), and (ii) chemical vapor deposition of the pristine-GF by ammoxidation reactions with NH3 -O2 reactants (continuous process). The properties of the electrodes are characterized, and the effects of doping methods and the kinetic relevance of the N and O co-functionalization are investigated for the VO 2+ /VO2 + redox reactions. The ammoxidative surface reaction of the GF with NH3 -O2 was highly effective for N and O co-doping with a significant formation of pyrrolic-N, pyridinic-N, quaternary-N, hydroxyl, and carbonyl functional groups with negligible degradation of the GF structure. The collective correlation analysis reveals that pyrrolic-N and hydroxyl are the most kinetically relevant molecular configurations of the N and O functional groups for facilitating VO 2+ /VO2 + redox kinetics. The N and O co-functionalized GF when utilized both for the cathode and anode electrodes for a VRFB afforded 3−4% greater initial voltage and energy efficiencies along with 1.6 times higher initial charge–discharge capacity than the conventional oxygen-doped GF electrode owing to the substantially lower reaction overpotential. The results elucidate the marked effects of N and O co-functionalization on the electrocatalytic activities of carbon electrodes for vanadium redox kinetics in VRFB.