A rotating rod electrode disk as an alternative to the rotating disk electrode for medium-temperature electrolytes, Part I: The effect of the absence of cylindrical insulation. (10th August 2017)

• Record Type: Journal Article
• Authors: Prokop, M.; Kodym, R.; Bystron, T.; Paidar, M.; Bouzek, K.
• Is Part Of: Electrochimica acta. Volume 245(2017)
• Page Start: 634
• Page End: 642
• Publication Date: 2017-08-10
• Subjects: rotating disk -- rotating rod disk -- mathematical modelling -- Levich equation -- fluid dynamics; Electrochemistry -- Periodicals; Electrochemistry, Industrial -- Periodicals; 541.37
• DOI: 10.1016/j.electacta.2017.05.123
• Languages: English
• ISSNs: 0013-4686

Abstract

Graphical abstract: Highlights: A rotating rod disk electrode (RRE) disk was introduced as an alternative to RDE. Comparison with RDE revealed higher limiting currents at RRE disk. A mathematical model was used to explain differences observed. Limiting current at RRE disk described by Levich equation with correction factor. RRE disk allows to determine kinetic parameters under controlled hydrodynamics. Abstract: In this paper, a rotating rod electrode disk is introduced as a hydrodynamic electrode and both the electrolyte flow hydrodynamics as well as mass transport towards the disk were investigated and compared with the rotating disk electrode. The main difference to the rotating disk is the absence of disk insulation leading to slightly enhanced mass transport towards the disk surface. Based on a combination of experiments and mathematical modelling for a broad range of kinematic viscosity values of the electrolyte solution, a correction of the Levich equation was introduced. This enables recalculation of the data determined using the rotating rod disk electrode so that they are equivalent to those of the rotating disk electrode. Although glassy carbon was used as the material of the rotating rod electrode in this work, in principle any other suitable material can be used. Thus, it can be concluded that the rotating rod electrode disk represents a cheap and effective tool easily applicable for measurements with controlled electrolyte convection in systems that are hardly manageable using a conventionally constructed rotating disk electrode. Good examples are melts or electrolyte solutions at temperatures above 80 °C. The applicability of the rotating rod electrode disk was successfully tested in the continuation (Part II) of this study. There, the thin-film modified (activated) rotating rod electrode disk was used for determining the mass transport properties of the oxygen and kinetic constants of the oxygen reduction reaction in concentrated phosphoric acid at 160 °C.