A triptycene-based two-dimensional porous organic polymeric nanosheet. Issue 36 (16th August 2017)
- Record Type:
- Journal Article
- Title:
- A triptycene-based two-dimensional porous organic polymeric nanosheet. Issue 36 (16th August 2017)
- Main Title:
- A triptycene-based two-dimensional porous organic polymeric nanosheet
- Authors:
- Chen, Jing-Jing
Zhai, Tian-Long
Chen, Yi-Fan
Geng, Shinan
Yu, Chan
Liu, Jun-Min
Wang, Linling
Tan, Bien
Zhang, Chun - Abstract:
- Abstract : A new application of the "old" Glaser coupling reaction for a two-dimensional porous polymeric nanosheet on an air/liquid interface is developed. Abstract : The greater structural versatility of two-dimensional polymeric nanosheets could be available through the development of a bottom-up polymerization strategy compared with top-down nanosheets (such as graphene and metal chalcogenides). However, rational synthesis by solution polymerization has been a long-standing challenge. Considering that Glaser coupling is catalyzed by cuprous (I) salts with the participation of oxygen, an air/liquid interfacial coupling reaction has been designed and used to prepare a two-dimensional porous triptycene-based polymeric nanosheet (2D-PTNS ). This2D-PTNS shows a high BET surface area, good gas adsorption ability and excellent selective adsorption of C2 H6 /CH4 at ambient temperature and pressure.
- Is Part Of:
- Polymer chemistry. Volume 8:Issue 36(2017)
- Journal:
- Polymer chemistry
- Issue:
- Volume 8:Issue 36(2017)
- Issue Display:
- Volume 8, Issue 36 (2017)
- Year:
- 2017
- Volume:
- 8
- Issue:
- 36
- Issue Sort Value:
- 2017-0008-0036-0000
- Page Start:
- 5533
- Page End:
- 5538
- Publication Date:
- 2017-08-16
- Subjects:
- Polymers -- Periodicals
Macromolecules -- Periodicals
Polymerization -- Periodicals
547.705 - Journal URLs:
- http://www.rsc.org/Publishing/Journals/PY/Index.asp ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/c7py01122a ↗
- Languages:
- English
- ISSNs:
- 1759-9954
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 6547.703400
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 4601.xml