Crown ether complexes of actinyls: a computational assessment of AnO2(15-crown-5)2+ (An = U, Np, Pu, Am, Cm). Issue 36 (11th September 2017)

• Record Type: Journal Article
• Authors: Hu, Shu-Xian; Li, Wan-Lu; Dong, Liang; Gibson, John K.; Li, Jun
• Is Part Of: Dalton transactions. Volume 46:Issue 36(2017)
• Page Start: 12354
• Page End: 12363
• Publication Date: 2017-09-11
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c7dt02825c
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : Computational characterization of AnO2 2+ –(15-crown-5) complexes (An = U, Np, Pu, Am, and Cm) reveals actinyl insertion coordination to crown ether. Abstract : For further fundamental understanding of the nature and extent of covalency in actinyl–ligand bonding, and the benefits that this may have in the design of new ligands for nuclear waste separation, there is burgeoning interest in the nature of actinyl complexes with polydentate or multiple-point-donor ligands, such as crown ethers. There are few cases of structurally authenticated molecular actinyl–crown bonds under ambient conditions. We report here the computational characterization of AnO2 2+ –(15-crown-5) complexes, where An = U, Np, Pu, Am, and Cm, and 15-crown-5 is the cyclic polyether ligand with five ether oxygen atoms. In the gas-phase complex, the actinyl group is located inside of the crown ether, tilted slightly out of the plane of the five equatorial oxygen atoms that coordinate the actinide metal center. The actinyl–cyclic ether complexes are found to exhibit a conventional conformation, with typical An–Oaxial and An–Oequatorial distances and angles. A striking result is the enhanced stability of the insertion complex for UO2 2+ versus NpO2 2+, PuO2 2+, AmO2 2+ and CmO2 2+, which is evaluated in the context of An–O binding strengths (esp. bonding covalency), and may have ramifications for the utility of actinyl-crown complexes in separation applications.