Direct transformation of 2-acetylpyridine oxime esters into α-oxygenated imines in an Ir(iii) complex. Issue 36 (30th August 2017)

• Record Type: Journal Article
• Authors: Takahashi, Hiroyuki; Kodama, Shintaro; Ishii, Youichi
• Is Part Of: Dalton transactions. Volume 46:Issue 36(2017)
• Page Start: 12032
• Page End: 12035
• Publication Date: 2017-08-30
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c7dt02528a
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : 2-Acetylpyridine oxime esters are transformed into the corresponding α-oxygenated imines in an Ir(iii ) complex under mild conditions. Abstract : 2-Acetylpyridine oxime esters are transformed into the corresponding α-oxygenated imines in an Ir(iii ) complex under mild conditions, where the selective metal coordination of the imino group effectively promotes tautomerization of the oxime esters into the N -oxyenamines and the subsequent rearrangement.