Calcium stilbene complexes: structures and dual reactivity. Issue 75 (6th September 2017)
- Record Type:
- Journal Article
- Title:
- Calcium stilbene complexes: structures and dual reactivity. Issue 75 (6th September 2017)
- Main Title:
- Calcium stilbene complexes: structures and dual reactivity
- Authors:
- Causero, Andrea
Elsen, Holger
Ballmann, Gerd
Escalona, Ana
Harder, Sjoerd - Abstract:
- Abstract : Addition of a calcium hydride complex to diphenylacetylene gave a complex in which the stilbene dianion symmetrically bridges two Ca 2+ ions. With H2, this complex reacts as a double Brønsted base. In reaction with I2 it provides two electrons. Abstract : Addition of a calcium hydride complex to diphenylacetylene gave a complex in which the stilbene dianion symmetrically bridges two Ca 2+ ions. DFT calculations discuss the effect of the metal stilbene coordination. The stilbene complex reacts as a base (with H2 ) or an electron donor (with I2 ) and catalyzes the reduction of diphenylacetylene.
- Is Part Of:
- Chemical communications. Volume 53:Issue 75(2017)
- Journal:
- Chemical communications
- Issue:
- Volume 53:Issue 75(2017)
- Issue Display:
- Volume 53, Issue 75 (2017)
- Year:
- 2017
- Volume:
- 53
- Issue:
- 75
- Issue Sort Value:
- 2017-0053-0075-0000
- Page Start:
- 10386
- Page End:
- 10389
- Publication Date:
- 2017-09-06
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/c7cc05792j ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 4597.xml