Photoinduced reversible spin-state switching of an FeIII complex assisted by a halogen-bonded supramolecular network. Issue 74 (4th September 2017)

• Record Type: Journal Article
• Authors: Jeon, Ie-Rang; Mathonière, Corine; Clérac, Rodolphe; Rouzières, Mathieu; Jeannin, Olivier; Trzop, Elzbieta; Collet, Eric; Fourmigué, Marc
• Is Part Of: Chemical communications. Volume 53:Issue 74(2017)
• Page Start: 10283
• Page End: 10286
• Publication Date: 2017-09-04
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/c7cc03797j
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : The organization of a molecular Fe III complex embedded in a halogen-bonded 2D network is chemically tuned to trigger temperature- and light-induced spin-state switching. Abstract : The organization of a molecular Fe III complex embedded in a halogen-bonded 2D network is chemically tuned to trigger temperature- and light-induced spin-state switching. We attribute the associated magnetic properties and the unprecedented photoswitching effect to the optimized structural confinement provided by the presence of the supramolecular host framework.