Immiscible silicate liquids and phosphoran olivine in Netschaëvo IIE silicate: Analogue for planetesimal core–mantle boundaries. (15th January 2017)

• Record Type: Journal Article
• Authors: Van Roosbroek, Nadia; Hamann, Christopher; McKibbin, Seann; Greshake, Ansgar; Wirth, Richard; Pittarello, Lidia; Hecht, Lutz; Claeys, Philippe; Debaille, Vinciane
• Is Part Of: Geochimica et cosmochimica acta. Volume 197(2017:Jan. 15)
• Page Start: 378
• Page End: 395
• Publication Date: 2017-01-15
• Subjects: Iron meteorites -- Impact melting -- Netschaëvo -- Silicate liquid immiscibility -- Core-mantle boundary; Geochemistry -- Periodicals; Meteorites -- Periodicals; Géochimie -- Périodiques; Météorites -- Périodiques; Geochemie; Astrochemie; Electronic journals; 551.905
• DOI: 10.1016/j.gca.2016.10.042
• Languages: English
• ISSNs: 0016-7037

Abstract

Abstract: We have investigated a piece of the Netschaëvo IIE iron meteorite containing a silicate inclusion by means of electron microprobe analysis (EMPA) and transmission electron microscopy (TEM). Netschaëvo contains chondrule-bearing clasts and impact melt rock clasts were also recently found. The examined inclusion belongs to the latter and is characterized by a porphyritic texture dominated by clusters of coarse-grained olivine and pyroxene, set in a fine-grained groundmass that consists of new crystals of olivine and a hyaline matrix. This matrix material has a quasi-basaltic composition in the inner part of the inclusion, whereas the edge of the inclusion has a lower SiO2 concentration and is enriched in MgO, P2 O5, CaO, and FeO. Close to the metal host, the inclusion also contains euhedral Mg-chromite crystals and small (<2 μm), Si-rich globules. A TEM foil was cut from this glassy, silico-phosphate material. It shows that the material consists of elongated olivine crystallites containing up to 14 wt% P2 O5, amorphous material, and interstitial Cl-apatite crystals. The Si-rich silicate glass globules show a second population of Fe-rich silicate glass droplets, indicating they formed by silicate liquid immiscibility. Together with the presence of phosphoran olivine and quenched Cl-apatite, these textures suggest rapid cooling and quenching as a consequence of an impact event. Moreover, the enrichment of phosphorus in the silicate inclusion close to the metal host (phosphoran olivine and Cl-apatite) indicates that phosphorus re-partitioned from the metal into the silicate phase upon cooling. This probably also took place in pallasite meteorites that contain late-crystallizing phases rich in phosphorus. Accordingly, our findings suggest that oxidation of phosphorus might be a general process in core–mantle environments, bearing on our understanding of planetesimal evolution. Thus, the Netschaëvo sample serves as a natural planetesimal core–mantle boundary experiment and based on our temperature estimates, the following sequence of events takes place: (i) precipitation of olivine (1400–1360 °C), (ii) re-partitioning of phosphorus from the metal into the silicate phase, and (iii) formation of immiscible melts (1230–1115 °C).